HKDSE-onward Chemistry Question Review

Question:

Draw the structure of Al_4C_3.

Solution:

Question:

Ca_2C reacts with water to give Ca(OH)_2. Write out another product.

Solutioon:

C_2H_2

Question:

(a) Draw the anion of a cryolite crystal.
(b) What is the use of this crystal?

Solution:

(a)

(b) Melting point depression

Question:

AlF_3 is added to the molten aluminum to decrease the solubility of the latter. What is this phenomenon called?

Solution:

Common ion effect

Question:

AlCl_3 is an active ingredient of common antiperspirant. Explain why excess use of it is harmful to human skins.

Solution:

AlCl_3 (aq) + 3H_2O (l) + heat \to Al(OH)_3 + 3HCl

As a result, acidic HCl will corrode your skin pore.

Quesion:

AlH_3 is a covalent crystal. Discuss how it can form an adduct.

Solution:

It is a Lewis acid. It reacts with a Lewis base to form an adduct:

AlH_3 + LiH \to LiAlH_4

Question:

Al_2Cl_6 is a solid. Explain why it sublimes upon heating.

Solution:

The dative bondings in Al_2Cl_6 (s) are rather weak. Upon heating, it decomposes into AlCl_3 (g)

Question:

Draw the structure of Bauxite.

Solution:

Question:

Suggest 2 impurities commonly found in Aluminum ores.

Solution:

Fe_2O_3, SiO_2

Question:

Silicates can be corroded by moisture. Explain briefly.

Solution:

Na_2SiO3 + CO_2 + H_2O \to NaHCO_3 + NaHSiO_3

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